English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

1,1-Bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane (TMCH) is a typical peroxide with two peroxy groups that may runaway and/or explode due to mixing with inorganic acids, such as HCl, HNO 3 , H 2 SO 4 , or H 3 PO 4 . In this study, reactivities of TMCH mixed with the above inorganic acids were assessed by differential scanning calorimetry (DSC). Furthermore, data obtained by DSC, such as exothermic onset temperature (T 0 ), maximum temperature (T max ), and heat of decomposition (ΔH d ) could be employed to acquire thermal safety parameters. Moreover, thermal activity monitor III (TAM III) was employed to investigate the thermal hazards while storing or transporting TMCH and TMCH mixed with four types of commonly used inorganic acids, here as HCl, HNO 3 , H 2 SO 4 , or H 3 PO 4 under isothermal conditions. Mixing TMCH with those inorganic acids resulted in higherΔH d except H 3 PO 4 , and mixing TMCH with HCl clearly decreased T 0 . Therefore, the phenomena of mixing those incompatible materials with TMCH can be concluded as the worst cases in terms of contamination hazards during storage and transportation of TMCH.

Thermal hazard assessment of TMCH mixed with inorganic acids