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International audienceHigh oxygen pressures are very suitable for the preparation of high oxidation states of transition elements. Using, in addition, appropriate structural and chemical bonding factors characterizing the anionic surrounding unusual electronic configurations can be obtained. The stabilization of Fe (V) in an OH site and high spin Fe (IV) or intermediate spin Co (III) in a D4H symmetry have been selected to illustrate these possibilities

HIGH OXYGEN PRESSURES AND RECENT DEVELOPMENTS IN THE FIELD OF HIGH OXIDATION STATES