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To explore nitric oxide (NO)-donating capability of Roussin’s red ester [Fe 2 (μ-RS) 2 (NO) 4 ] (RRE), photodissociation of NO from RRE and its subsequent reaction dynamics were probed by monitoring the N–O stretching mode after excitation with a 400-nm photon. As a result of the experiment, the NO generation quantum yield was obtained.

Photodissociation dynamics of nitric oxide from roussin’s red ester probed by time-resolved infrared spectroscopy