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We study the field and temperature dependences of the magnetization (B≤7.5 T, T=2.0-75 K) of samples from a single crystal Pb 1-x-y Sn x V y Te (x=0.08, y=0.01) ingot synthesized by the Bridgman method. It is established that the magnetization of the samples contains two main contributions: the Brillouin-type paramagnetism of vanadium ions and the diamagnetism of the crystal lattice. Experimental field and temperature dependences of the magnetization are discussed in the framework of a theoretical model of electronic structure rearrangement in Pb 1-x-y Sn x V y Te with doping and approximated as the sums of two terms based on the modified Brillouin functions for vanadium ions in the V 3+  and V 2+  states. The concentrations of magnetically active vanadium ions in two different charge states with increasing impurity concentration along the ingot are determined.

Magnetic properties of Pb1-x-ySnxVyTe alloys

Magnetic properties of Pb₁-_x-_ySn_xV_yTe alloys