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The study of LH2 protein of purple bacteria by broadband 2D electronic spectroscopy is presented. The dark 1Bu- carotenoid state is directly observed in 2D spectra and its role in carotenoid-bacteriochlorophyll interaction is discussed

epj web of conferences

Broadband 2D Electronic Spectroscopy Reveals Coupling Between Dark 1Bu-State of Carotenoid and QxState of Bacteriochlorophyll