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Ultrafast pump-probe spectroscopy, time-resolved x-ray absorption, and computational photochemistry elucidate the photochemical pathway of hexabromoplatinate dianions that propagates through distortions of nascent penta-bromoplatinate anions caused by Jahn-Teller conical intersections and terminates at aquated product complexes

Short-Time Events, Coherence, and Structural Dynamics in Photochemistry of Aqueous Halogenated Transition Metal Dianions