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The solid-liquid phase equilibrium for ternary system (NH2)2CO+KCl+H2O was determined by isothermal saturation method at 283.15K under atmosphere pressure. The isothermal phase diagrams was drawn in according to the measured solubility data. There are one co-saturated point and two pure solids occurred in this ternary system. The solid phases were confirmed by Schreinemaker’s wet residue method and X-ray powder diffraction. Two thermodynamic models, Wilson model and NRTL model, were used to calculate the solubility data. The value of root mean-square deviation in Wilson model and NRTL model for this ternary system was 0.22 and 0.66 respectively, and the value of relative average deviation was 0.61% and 2.33% respectively, which indicated that the calculated data and the experimental results are nearly consistent.

Determination and Calculation of Phase Equilibrium for Aqueous Ternary System (NH2)2CO+KCl+H2O at 283.15K

Determination and Calculation of Phase Equilibrium for Aqueous Ternary System (NH₂)₂CO+KCl+H₂O at 283.15K