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This paper describes the construction and assessment of the operating characteristics and analytical usefulness of a homogeneous crystalline silver double membrane tubular electrode with increased sensitivity. The constructed electrodes allowed Ag(I) determinations in the 3 10 -5 - 1 10 -1 M range with a calibration slope of 114 mV dec -1 and with good reproducibility (0.6 mV). The development and application of a flow injection analysis system manifold for chloride determinations in wine samples, in a wide concentration range (10 - 800 mg l -1 ), with a titrant consumption of 90 μg determination -1 is also described. The results obtained from the analysis of 12 wine samples showed good agreement between the proposed method and the reference one, accomplishing 90 - 200 samples h -1 .

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Construction and evaluation of a crystalline silver double-membrane tubular potentiometric detector for flow injection analysis. Application to chloride determination in wine