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A 'ketomethylene' peptide, N-benzyloxycarbonyl-L-prolyl-L-alanyl-3-amino- 2-oxopropyl-L-leucyl-L-alanylglycine ethyl ester, was synthesized and shown to be a fairly potent competitive inhibitor of human skin collagenase.

biochemical journal

Competitive inhibition of human skin collagenase by <i>N</i>-benzyloxycarbonyl-<scp>l</scp>-prolyl-<scp>l</scp>-alanyl-3-amino-2-oxopropyl-<scp>l</scp>-leucyl-<scp>l</scp>- alanylglycine ethyl ester

Competitive inhibition of human skin collagenase by N-benzyloxycarbonyl-l-prolyl-l-alanyl-3-amino-2-oxopropyl-l-leucyl-l- alanylglycine ethyl ester