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The simple inorganic cyclodiphosph( iii )azane chiral derivatisation agent ClP(μ-  t  BuN) 2 POBorn (Born =  endo -(1 S )-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl) is shown to be effective in the measurement of  ee ’s of chiral amines using  31 P NMR spectroscopy.

A chiral phosphazane reagent strategy for the determination of enantiomeric excess of amines