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An enantioselective IEDDA reaction between 2-pyrone and cyclic enamine was realized to construct  cis -hydroindoles in high yield and ee, providing a concise route for formal total synthesis of (+)-minovincine.

chemical science

Enantioselective construction of <i>cis</i>-hydroindole scaffolds <i>via</i> an asymmetric inverse-electron-demand Diels–Alder reaction: application to the formal total synthesis of (+)-minovincine

Enantioselective construction of cis-hydroindole scaffolds via an asymmetric inverse-electron-demand Diels–Alder reaction: application to the formal total synthesis of (+)-minovincine