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Benzylic/allylic alcohols are converted  via  site-selective C(sp 2 )–C(sp 3 ) cleavage to value-added nitrogenous motifs,  viz. , anilines and/or nitriles as well as N-heterocycles, utilizing commercial hydroxylamine- O -sulfonic acid (HOSA) and Et 3 N in an operationally simple, one-pot process.

Site-selective amination and/or nitrilationviametal-free C(sp2)–C(sp3) cleavage of benzylic and allylic alcohols

Site-selective amination and/or nitrilationviametal-free C(sp²)–C(sp³) cleavage of benzylic and allylic alcohols