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A direct reductive cross-dialkylation of alkynes is achieved to afford  trans -dialkylated olefins using two distinct alkyl bromides. The reaction undergoes with exclusive chemo-, regio- and stereoselectivity without the use of organometallic reagents.

chemical science

Rapid access to t-butylalkylated olefins enabled by Ni-catalyzed intermolecular regio- and trans-selective cross-electrophile t-butylalkylation of alkynes