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A tetra( o -tolyl)(μ-hydrido)diborane(4) anion is facilely prepared  via  the reaction of tetra( o -tolyl)diborane(4) with NaH. It exhibits a σ-B–B bond nucleophilicity towards NHC-metal halides to give the corresponding η 2 -B–B bonded metal complexes.

A (μ-hydrido)diborane(4) anion and its coordination chemistry with coinage metals