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Three mild and operationally simple fluorination protocols convert 1-alkynyl triazenes either into attractive 1,1,2,2-tetrafluoro alkyl triazenes, α-difluoro α-triazenyl ketones or α-difluoro acyl triazenes.

Chemo- and regio-divergent access to fluorinated 1-alkyl and 1-acyl triazenes from alkynyl triazenes