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Un-protected 2-acetamido sugars are stereoselectively converted into 1,2- trans  glycosides and (1→6)-linked disaccharides without any protecting groups. Reaction proceeds  via  intermediate oxazolines which react with acceptors under acid catalysis.

chemical science

Protecting group free glycosylation: one-pot stereocontrolled access to 1,2-<i>trans</i> glycosides and (1→6)-linked disaccharides of 2-acetamido sugars

Protecting group free glycosylation: one-pot stereocontrolled access to 1,2-trans glycosides and (1→6)-linked disaccharides of 2-acetamido sugars