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For the first time site-specific doping of silver into a spherical Au 25  nanocluster has been achieved in [Au 19 Ag 6 (MeOPhS) 17 (PPh 3 ) 6 ] (BF 4 ) 2 . It is a 6e system showing quite a different absorption spectrum from [Au 25 (SR) 18 ] − .

Site-specific doping of silver atoms into a Au25 nanocluster as directed by ligand binding preferences

Site-specific doping of silver atoms into a Au₂₅ nanocluster as directed by ligand binding preferences