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The first stereocontrolled total synthesis of 4( S ),5( S )-oxido-17( S )-hydroxy-6( E ),8( E ),10( Z ),13( Z ),15( E ),19( Z )-docosahexaenoic acid (1) is reported.

rsc advances

First stereoselective total synthesis of 4(S),5(S)-oxido-17(S)-hydroxy-6(E),8(E),10(Z),13(Z),15(E),19(Z)-docosahexaenoic acid, the biosynthetic precursor of resolvins D3 and D4