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Lithiation of silicon in an LiFSI electrolyte results in a bilayer SEI, with an inner, inorganic layer, and an outer, organic. This SEI is more conductive, flexible and homogeneous compared to the SEI formed in an LiPF 6  electrolyte.

rsc advances

Improved electrochemical performance and solid electrolyte interphase properties of electrolytes based on lithium bis(fluorosulfonyl)imide for high content silicon anodes