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Pd(200) and the Pd(200)/PdO(102, 110) interface generated  in situ  participated in coupling reactions  via  a synergistic effect, boosting the catalytic activity to a high level.

rsc advances

Pd–Pd/PdO as active sites on intercalated graphene oxide modified by diaminobenzene: fabrication, catalysis properties, synergistic effects, and catalytic mechanism