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A novel thiophene derivative, namely 2,5-diisopropenylthiophene (DIT) was synthetized by Suzuki–Miyaura cross-coupling reaction (SMCCR) and employed in the inverse vulcanization (IV) process achieving high-refractive-index sulfur-rich polymers.

2,5-Diisopropenylthiophene by Suzuki–Miyaura cross-coupling reaction and its exploitation in inverse vulcanization: a case study