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A N 6 -tripodal ligand allows the preparation of a family of prismatic mononuclear cationic Co II  complexes with SMM behavior. Their axial anisotropy, magnetic relaxation and hysteresis width are modulated by the anion effects on the crystal structure.

inorganic chemistry frontiers

Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt(<scp>ii</scp>) complexes with zero-field hidden single-molecule magnet behaviour: the important role of the distortion of the coordination sphere and intermolecular interactions in the slow relaxation

Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt(ii) complexes with zero-field hidden single-molecule magnet behaviour: the important role of the distortion of the coordination sphere and intermolecular interactions in the slow relaxation