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We provide a detailed understanding of the HER mechanism of Ti 3 C 2  MXene by revealing the origin of the high overpotential exhibited by the material using  in situ /operando Raman spectroelectrochemistry and density functional theory calculations.

Hydrogen evolution reaction mechanism on Ti3C2 MXene revealed by in situ/operando Raman spectroelectrochemistry

Hydrogen evolution reaction mechanism on Ti₃C₂ MXene revealed by in situ/operando Raman spectroelectrochemistry