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The heteroleptic mer-[Cr(L)(CN) 3 ] (L = tpy, ddpd, dqp) complexes with their  C  2v -symmetrical [CrC 3 N 3 ] luminescent chromophores represent the missing links between pseudo-octahedral [CrN 6 ] and [CrC 6 ] units found in their well-known homoleptic parents.

dalton transactions

Heterolepticmer-[Cr(N∩N∩N)(CN)3] complexes: synthetic challenge, structural characterization and photophysical properties