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A new tridimensional metal-organic chalcogenolate, made of a 1,3-benzenedithiolate bridging ligand and Ag(I), [Ag 2 (1,3-BDT)]  n  , is reported. This coordination polymer has good thermal stability in air and displays both photoluminescence properties and a second harmonic generation response.

A chiral 3D silver(i)–benzenedithiolate coordination polymer exhibiting photoemission and non-linear optical response