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The interaction of a [bis(pyridine)iodine( i )] +  cation with a [bis(pyridine)silver( i )] +  cation, in which an iodonium ion acts as a nucleophile by transferring electron density to the silver( i ) cation, is reinvestigated herein.

Do 2-coordinate iodine(i) and silver(i) complexes form nucleophilic iodonium interactions (NIIs) in solution?