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The commercially available difluoromethyltrimethylsilane acts as a valuable difluoromethylating agent for heteroatom-based electrophiles. Upon activation with an alkoxide, a nucleophilic displacement furnishes the corresponding bench-stable analogues.

chemical communications

Straightforward synthesis of bench-stable heteroatom-centered difluoromethylated entities <i>via</i> controlled nucleophilic transfer from activated TMSCHF<sub>2</sub>

Straightforward synthesis of bench-stable heteroatom-centered difluoromethylated entities via controlled nucleophilic transfer from activated TMSCHF2

Straightforward synthesis of bench-stable heteroatom-centered difluoromethylated entities via controlled nucleophilic transfer from activated TMSCHF₂