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Cucurbit[7]uril accelerates acid hydrolysis and screens the reaction centre from the neighbouring group. The coordination of alkali metal cations to the macrocycle portal uncompetitively reduces the catalytic activity.

Effect of Na+ and K+ on the cucurbituril-mediated hydrolysis of a phenyl acetate

Effect of Na⁺ and K⁺ on the cucurbituril-mediated hydrolysis of a phenyl acetate