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Herein is described a blue-emitting gold( iii )–TADF complex serving as a sensitizer for SP-OLEDs, in which an MR-TADF emitter is employed as the emissive dopant. The SP-OLEDs attained EQE max  of up to 16.6%, high color purity and CIE  x,y   of (0.14, 0.18).

A gold(iii)–TADF emitter as a sensitizer for high-color-purity and efficient deep-blue solution-processed OLEDs