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An asymmetric carbazole-donor motif in a D–A–D type naphthyridine-based TADF emitter enables CT/LE state mixing, thus enhancing the RISC rate, shortening the delayed fluorescence lifetime and reducing the OLED efficiency roll-off.

Enhanced blue TADF in a D–A–D type naphthyridine derivative with an asymmetric carbazole-donor motif