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A structural study from synchrotron X-ray and neutron diffraction of an undeuterated FAPbBr 3  specimen allows identification of two phase transitions ( Pm 3̄ m → P 4/ mbm → Pnma ). Further rearrangements in the H bonds to Br imply thermal events observed by calorimetric measurements.

On the crystal structure thermal evolution of formamidinium lead tribromide, CH(NH2)2PbBr3

On the crystal structure thermal evolution of formamidinium lead tribromide, CH(NH₂)₂PbBr₃