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Two small donors with alkyl chains close to (Se-1) and away from (Se-2) the donor core were synthesized. Ordered molecular packing and an induced face-on packing by PJ1 enable an efficient charge generation and low  V  oc  loss in the Se-2/PJ1 device.

Efficient charge generation and low open circuit voltage loss enable a PCE of 10.3% in small molecule donor and polymer acceptor organic solar cells