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Enantiopure semiconducting crystalline radical cation salts of TM-BEDT-TTF with the Lindqvist type molybdenum based dianion, prepared by electrocrystallization, show unusual donor/anion ratio, charge distribution and helical packing of the donors.

journal of materials chemistry. c

Unusual stoichiometry, band structure and band filling in conducting enantiopure radical cation salts of TM-BEDT-TTF showing helical packing of the donors