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Functionalising 2,5-di( N,N' -carbazolyl)terephthalonitrile or 2,3,5,6-tetra( N,N' -carbazolyl)terephthalonitrile on the carbazole moiety with alkoxy chains, gives a family of materials that show TADF response; two of them are also liquid crystalline.

Liquid-crystalline TADF materials based on substituted carbazoles and terephthalonitrile