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Starting with potassium acyltrifluoroborates (KATs),  N -unprotected chiral α-aminoboronic acids are prepared in three simple steps without chromatography. This facile methodology will tap the broad potential of these valuable compounds.

chemical science

Primary trifluoroborate-iminiums enable facile access to chiral α-aminoboronic acids <i>via</i> Ru-catalyzed asymmetric hydrogenation and simple hydrolysis of the trifluoroborate moiety

Primary trifluoroborate-iminiums enable facile access to chiral α-aminoboronic acids via Ru-catalyzed asymmetric hydrogenation and simple hydrolysis of the trifluoroborate moiety