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We have created a family of ‘encapsulated sandwich’ Zn 16 Ln(HA) 16  metallacrowns and by detailed quantitative analysis demonstrated how the nature of the hydroximate ligand impacts photophysical properties of these complexes.

chemical science

Tuning the photophysical properties of lanthanide(<scp>iii</scp>)/zinc(<scp>ii</scp>) ‘encapsulated sandwich’ metallacrowns emitting in the near-infrared range

Tuning the photophysical properties of lanthanide(iii)/zinc(ii) ‘encapsulated sandwich’ metallacrowns emitting in the near-infrared range