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Dehydrofluorination of a fluorinated vinyl ligand takes place after C–H bond activation of  Z -1,3,3,3-tetrafluropropene at a rhodium vinyl complex. Model studies support a vinylidene as reaction intermediate for the dehydrofluorination.

chemical science

Competing C–H and C–F bond activation reactions of a fluorinated olefin at Rh: a fluorido vinylidene complex as an intermediate in an unprecedented dehydrofluorination step