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A new class of biaryl chiral ligands derived from 1,2-diaminocyclohexane (DACH) has been designed to enable the asymmetric addition of aliphatic and, for the first time, aromatic Grignard reagents to...

chemical science

Asymmetric addition of Grignard reagents to ketones: culmination of the ligand-mediated methodology allows modular construction of chiral tertiary alcohols