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An inter-particle reaction between atomically precise [Au 44 (SR) 26 ] 2−  (SR = thiolate) and [Ag 44 (SR) 30 ] 4−  nanoparticles reveals the composition-dependent structural evolution of alloy Au  x  Ag 44− x   nanoparticles at the atomic level.

Revealing the composition-dependent structural evolution fundamentals of bimetallic nanoparticles through an inter-particle alloying reaction