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Hexakis( meta -fluoro)substituted triphenylmethyl cation (F 6 Tr + ) was isolated with a carborane partner anion. Its significantly higher hydride affinity compared to the parent (Tr + ) allows it to abstract hydrides from a variety of C(sp 3 )–H bonds.

Isolable fluorinated triphenylmethyl cation salts of [HCB11Cl11]−: demonstration of remarkable hydride affinity

Isolable fluorinated triphenylmethyl cation salts of [HCB₁₁Cl₁₁]⁻: demonstration of remarkable hydride affinity