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An N–CH 3 -selective trialkylamine oxidation to  N -formamides is reported in continuous flow using gaseous O 2 . A novel, enhanced-solubility dicyanoanthracene organophotocatalyst switched the photochemical mechanism from electron to energy transfer.

An organophotocatalytic late-stage N–CH3oxidation of trialkylamines toN-formamides with O2in continuous flow

An organophotocatalytic late-stage N–CH₃oxidation of trialkylamines toN-formamides with O₂in continuous flow