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Exceptionally slow autodetachment dynamics of the vibrational Feshbach resonances found in the dipole-bound state of 4-bromophonoxide (4-BrPhO − ) or 4-chlorophenoxide (4-ClPhO − ) anions reveals the associated dynamic role of the correlation effect.

chemical science

Dynamic role of the correlation effect revealed in the exceptionally slow autodetachment rates of the vibrational Feshbach resonances in the dipole-bound state