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Nobler than expected: subvalent [Ga(PhF) 2 ][ pf ] ([ pf ] −  = [Al{OC(CF 3 ) 3 } 4 ] − ) oxidizes hydrosilanes to silylium ions, allowing for catalytic hydrosilylation and hydrodefluorination and suggesting that silylium catalysis is possible with the [ pf ]− anion.

chemical science (cambridge. 2010. print)

Ga+-catalyzed hydrosilylation? About the surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+ and silylium catalysis with perfluoroalkoxyaluminate anions