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By performing a swarm-intelligent global structure search combined with first-principles calculations, a stable 2D AlB 3  heterostructure with directed, covalent Al–B bonds forms due to a nearly perfect lattice match between 2D borophene and the Al(111) surface.

chemical science

A perfect match between borophene and aluminium in the AlB<sub>3</sub> heterostructure with covalent Al–B bonds, multiple Dirac points and a high Fermi velocity

A perfect match between borophene and aluminium in the AlB3 heterostructure with covalent Al–B bonds, multiple Dirac points and a high Fermi velocity

A perfect match between borophene and aluminium in the AlB₃ heterostructure with covalent Al–B bonds, multiple Dirac points and a high Fermi velocity