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Copper–ethylene and carbonyl complexes of the newly developed [Ph 2 B(3-(SF 5 )Pz) 2 ] −  enable the study of ligand steric and electronic effects caused by the –SF 5  group (dubbed “super CF 3 ”), and a comparison to the –CF 3  bearing analogs.

When SF5 outplays CF3: effects of pentafluorosulfanyl decorated scorpionates on copper

When SF₅ outplays CF₃: effects of pentafluorosulfanyl decorated scorpionates on copper