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A homogeneous nickel catalyst is described that forms ( n +1)-membered cycloalkane rings from ketones and 1, n -diols following a radical-promoted pathway.

chemical science

Ligand-redox assisted nickel catalysis toward stereoselective synthesis of (<i>n</i>+1)-membered cycloalkanes from 1,<i>n</i>-diols with methyl ketones

Ligand-redox assisted nickel catalysis toward stereoselective synthesis of (n+1)-membered cycloalkanes from 1,n-diols with methyl ketones