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Treatment of hexachloropropene (Cl 2 CC(Cl)–CCl 3 ) with Si 2 Cl 6  and [ n Bu 4 N]Cl (1 : 4 : 1) in CH 2 Cl 2  results in a quantitative conversion to the trisilylated, dichlorinated allyl anion salt [ n Bu 4 N][Cl 2 CC(SiCl 3 )–C(SiCl 3 ) 2 ] ([ n Bu 4 N][1]).

The power of trichlorosilylation: isolable trisilylated allyl anions, allyl radicals, and allenyl anions