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A readily available disilane Me 3 SiSiMe 2 (O  n  Bu) as a silylene source has been developed for the synthesis of diverse silacycles  via  Brook- and retro-Brook-type rearrangement.

chemical science

Me3SiSiMe2(OnBu): a disilane reagent for the synthesis of diverse silacycles via Brook- and retro-Brook-type rearrangement