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We report a unified chemoenzymatic asymmetric synthesis of five prostaglandins, featuring two enzymatic redox transformations and a copper( ii )-catalyzed regioselective  p -phenylbenzoylation.

chemical science

A unified strategy to prostaglandins: chemoenzymatic total synthesis of cloprostenol, bimatoprost, PGF<sub>2α</sub>, fluprostenol, and travoprost guided by biocatalytic retrosynthesis

A unified strategy to prostaglandins: chemoenzymatic total synthesis of cloprostenol, bimatoprost, PGF2α, fluprostenol, and travoprost guided by biocatalytic retrosynthesis

A unified strategy to prostaglandins: chemoenzymatic total synthesis of cloprostenol, bimatoprost, PGF_2α, fluprostenol, and travoprost guided by biocatalytic retrosynthesis