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A series of chiral Au 13  nanoclusters were synthesized  via  the direct reduction of achiral dinuclear Au( i ) halide complexes ligated by  ortho -xylyl-linked bis- N -heterocyclic carbene (NHC) ligands.

Synthesis and enantioseparation of chiral Au13 nanoclusters protected by bis-N-heterocyclic carbene ligands

Synthesis and enantioseparation of chiral Au₁₃ nanoclusters protected by bis-N-heterocyclic carbene ligands